Search results for "concomitant transmetalation"

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Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(II)-framework.

2015

A 3D cationic Zn(II) framework, based on Zn2(CO2)4 paddle-wheel secondary building units (SBUs) and Zn16(CO2)32 polyhedral supramolecular building blocks (SBBs), has been synthesized. At room temperature, the framework undergoes guest solvent triggered reversible structural transformation and concomitant Zn(II) to Cu(II) transmetalation in a single-crystal to single-crystal fashion.

Chemistryconcomitant transmetalationMetals and AlloysCationic polymerizationSupramolecular chemistryGeneral Chemistrystructural transformationPhotochemistrysingle crystalsCatalysisStructural transformationSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSolventTransmetalationPolymer chemistryMaterials ChemistryCeramics and CompositesSBusSingle crystalta116Chemical communications (Cambridge, England)
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